MARIALITE
Chemical formula: Na4Al3Si9O24Cl
Family: Silicates
Status: IMA-GP
Crystal system : Tetragonal
Display mineral: NON
Associated names (luminescent varieties, discredited names, synonyms, etc.): dipyre,
Luminescence:
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Longwave UV (365nm) colors: | Yellow ,
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Shortwave UV (254nm) colors: | Orange , Orange Red , Red ,
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Phosphorescence (in the common sense of the term) observable with the naked eye:
No data
Comments:
Mineral of the group SCAPOLITE ( see also MEIONITE).
Marialite and meionite are found as masses or blocky crystals in a number of localities in the Grenville marble of Quebec and ontario (Canada). Sometimes (opaque white crystals from Otter Lake, Quebec) fluo red SW (activator: Fe) and white LW.
Activator(s) and spectrum:
Activator(s): Mn2+ , S2-, Fe3+, Eu2+, O-2,
Peaks in the spectrum (nm):
(O2)- replacing Cl- (?) : weak band around 500nm
(S2)- replacing Cl- (?) : another weak band around 600nm
Mn2+ replacing Ca2+ (?) : peak at 700nm
Fe3+ replacing Al3+ : side band around 750nm
No spectrum yet
Best localities for fluorescence (*):
- Bancroft, Ontario, Canada (wernerite);
- Gooderham area, Haliburton Co., Ontario, Canada (weak red SW);
- Otter Lake, Quebec, Canada (wernerite) (bright yellow-orange LW, weaker SW);
- Franklin, New jersey, USA;
- Karur, Tamilnadu, India (red SW);
- Old Mine Park, Long Hill, Trumbull, Fairfield Co., Connecticut, USA (pink-lavender SW);
- Pitwak Mine, Koksha Valley, Khash & Kuran Wa Munjan Districts, Badakhshan Province, Afghanistan (pseodomorph after orthoclase, bright yellow LW);
(*)The data are not exhaustive and are limited to a few remarkable localities for fluorescence
Bibliographic reference for luminescence:
- The Henkel Glossary of Fluorescent Minerals, Dr. Gerhard Henkel, Published by the FMS, 1989 ,
- Fluorescence: Gems and Minerals Under Ultraviolet Light, Manuel Robbins, 1994, Geoscience Press, ISBN 0-945005-13-X ,
- Luminescent Spectra of Minerals, Boris S. Gorobets and Alexandre A. Rogojine, Moscow, 2002 ,
Reference for luminescence on the Internet:
- Mineral van de maand: marialiet, door Rik Dillen, Herwig Pelckmans, Axel Emmermann, Georges Claeys in Geonieuws, newletter of the MKA, december 2010;
Images:
Mineralogical reference on the Internet:
http://www.mindat.org/show.php?name=Marialite
http://webmineral.com/data/Marialite.shtml
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